5Al3+ + 8[Al(OH)4]− → Al13O4(OH)247+ + 4H2O
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The reaction of aluminium ion and tetrahydroxidoaluminate ion yields tridecaaluminium tetracosahydroxide tetraoxide ion and water (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of aluminium ion and tetrahydroxidoaluminate ion
General equation
- Reaction of cation and anion
- CationLewis acid + AnionLewis base ⟶ ProductLewis conjugate + (H2O)
Oxidation state of each atom
- Reaction of aluminium ion and tetrahydroxidoaluminate ion
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Al3+ | Aluminium ion | 5 | Lewis acid | Cation |
| [Al(OH)4]− | Tetrahydroxidoaluminate ion | 8 | Lewis base | Anion |
Products
Thermodynamic changes
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Al3+ (g) | 5483.17[1] | – | – | – |
| Al3+ (ao) | -531[1] | -485[1] | -321.7[1] | – |
| [Al(OH)4]− (ao) | -1502.5[1] | -1305.3[1] | 102.9[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Al13O4(OH)247+ | – | – | – | – |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (l):Liquid, (g):Gas
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 5483.17 kJ · mol−1
- ^ ΔfH°, -531. kJ · mol−1
- ^ ΔfG°, -485. kJ · mol−1
- ^ S°, -321.7 J · K−1 · mol−1
- ^ ΔfH°, -1502.5 kJ · mol−1
- ^ ΔfG°, -1305.3 kJ · mol−1
- ^ S°, 102.9 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1