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5H3AsO3 🔥→ 3H3AsO4 + 2As + 3H2O

Decomposition of arsenous acid yields arsenic acid, arsenic, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Thermal decomposition with redox
Thermally decomposable substanceSelf redox agent
🔥
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Decomposition of arsenous acid

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
H3AsO3Arsenous acid5
Thermally decomposable

Products

Chemical formulaNameCoefficientTypeType in general
equation
H3AsO4Arsenic acid3
Oxidized
AsArsenic2
Reduced
H2OWater3

Thermodynamic changes

Changes in standard condition (1)

Decomposition of arsenous acid
ΔrG189.6 kJ/mol
K0.61 × 10−33
pK33.22
5H3AsO3Un-ionized aqueous solution
🔥
3H3AsO4Un-ionized aqueous solution + 2AsCrystalline solidα, gray, metallic + 3H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
146.0189.6−143
per 1 mol of
29.2037.92−28.6
per 1 mol of
48.6763.20−47.7
per 1 mol of
73.0094.80−71.5
per 1 mol of
48.6763.20−47.7

Changes in standard condition (2)

Decomposition of arsenous acid
5H3AsO3Un-ionized aqueous solution
🔥
3H3AsO4Aqueous solution + 2AsCrystalline solidα, gray, metallic + 3H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
139.7
per 1 mol of
27.94
per 1 mol of
46.57
per 1 mol of
69.85
per 1 mol of
46.57

Changes in standard condition (3)

Decomposition of arsenous acid
5H3AsO3Aqueous solution
🔥
3H3AsO4Un-ionized aqueous solution + 2AsCrystalline solidα, gray, metallic + 3H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
146.0
per 1 mol of
29.20
per 1 mol of
48.67
per 1 mol of
73.00
per 1 mol of
48.67

Changes in standard condition (4)

Decomposition of arsenous acid
5H3AsO3Aqueous solution
🔥
3H3AsO4Aqueous solution + 2AsCrystalline solidα, gray, metallic + 3H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
139.7
per 1 mol of
27.94
per 1 mol of
46.57
per 1 mol of
69.85
per 1 mol of
46.57

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
H3AsO3 (ao)-742.2[1]-639.80[1]195.0[1]
H3AsO3 (aq)-742.2[1]
* (ao):Un-ionized aqueous solution, (aq):Aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
H3AsO4 (cr)-906.3[1]
H3AsO4 (ao)-902.5[1]-766.0[1]184[1]
H3AsO4 (aq)-904.6[1]
As (cr)
α, gray, metallic
0[1]0[1]35.1[1]24.64[1]
As (cr)
γ, yellow, cubic
14.6[1]
As (am)
β
4.2[1]
As (g)302.5[1]261.0[1]174.21[1]20.786[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (ao):Un-ionized aqueous solution, (aq):Aqueous solution, (am):Amorphous solid, (g):Gas, (l):Liquid

References

List of references

  1. 1