5Cu + 2CsClO3 + 12H+ → 5Cu2+ + Cl2↑ + 2Cs+ + 6H2O
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- Reaction of and caesium chlorate under acidic condition
- 5 + 2CsClO3Caesium chlorate + 12H+Hydrogen ion5Cu2+Copper(II) ion + ↑ + 2Cs+Caesium ion + 6H2OWater⟶
The reaction of , caesium chlorate, and hydrogen ion yields copper(II) ion, , caesium ion, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and caesium chlorate under acidic condition
- 5 + 2CsClO3Caesium chlorate + 12H+Hydrogen ion5Cu2+Copper(II) ion + ↑ + 2Cs+Caesium ion + 6H2OWater⟶
General equation
- Reaction of oxidizable species and oxidizing species under acidic condition
- Oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent + H+Non-redox agent ⟶ ProductOxidation product + ProductReduction product + H2ONon-redox product
Oxidation state of each atom
- Reaction of and caesium chlorate under acidic condition
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
5 | Reducing | Oxidizable | ||
CsClO3 | Caesium chlorate | 2 | Oxidizing | Oxidizing under acidic condition |
H+ | Hydrogen ion | 12 | – | Hydrogen ion |
Products
Thermodynamic changes
Changes in standard condition (1)
- Reaction of and caesium chlorate under acidic condition◆
ΔrG −1079.42 kJ/mol K 1.28 × 10189 pK −189.11
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −1183.19 | −1079.42 | −345.9 | – |
−236.638 | −215.884 | −69.18 | – | |
per 1 mol of | −591.595 | −539.710 | −172.9 | – |
per 1 mol of Hydrogen ion | −98.5992 | −89.9517 | −28.82 | – |
per 1 mol of Copper(II) ion | −236.638 | −215.884 | −69.18 | – |
−1183.19 | −1079.42 | −345.9 | – | |
per 1 mol of Caesium ion | −591.595 | −539.710 | −172.9 | – |
per 1 mol of | −197.198 | −179.903 | −57.65 | – |
Changes in standard condition (2)
- Reaction of and caesium chlorate under acidic condition◆
ΔrG −1072.48 kJ/mol K 7.77 × 10187 pK −187.89
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −1206.6 | −1072.48 | −448 | – |
−241.32 | −214.496 | −89.6 | – | |
per 1 mol of | −603.30 | −536.240 | −224 | – |
per 1 mol of Hydrogen ion | −100.55 | −89.3733 | −37.3 | – |
per 1 mol of Copper(II) ion | −241.32 | −214.496 | −89.6 | – |
−1206.6 | −1072.48 | −448 | – | |
per 1 mol of Caesium ion | −603.30 | −536.240 | −224 | – |
per 1 mol of | −201.10 | −178.747 | −74.7 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(cr) | 0[1] | 0[1] | 33.150[1] | 24.435[1] |
(g) | 338.32[1] | 298.58[1] | 166.38[1] | 20.786[1] |
CsClO3 (cr) | -411.7[1] | -307.9[1] | 156.1[1] | – |
CsClO3 (ai) | -362.25[1] | -299.97[1] | 295.4[1] | – |
H+ (g) | 1536.202[1] | – | – | – |
H+ (ao) | 0[1] | 0[1] | 0[1] | 0[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Cu2+ (g) | 3054.07[1] | – | – | – |
Cu2+ (ao) | 64.77[1] | 65.49[1] | -99.6[1] | – |
(g) | 0[1] | 0[1] | 223.066[1] | 33.907[1] |
(ao) | -23.4[1] | 6.94[1] | 121[1] | – |
Cs+ (g) | 457.964[1] | – | – | – |
Cs+ (ao) | -258.28[1] | -292.02[1] | 133.05[1] | -10.5[1] |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (l):Liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 33.150 J · K−1 · mol−1
- ^ Cp°, 24.435 J · K−1 · mol−1
- ^ ΔfH°, 338.32 kJ · mol−1
- ^ ΔfG°, 298.58 kJ · mol−1
- ^ S°, 166.38 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1
- ^ ΔfH°, -411.7 kJ · mol−1
- ^ ΔfG°, -307.9 kJ · mol−1
- ^ S°, 156.1 J · K−1 · mol−1
- ^ ΔfH°, -362.25 kJ · mol−1
- ^ ΔfG°, -299.97 kJ · mol−1
- ^ S°, 295.4 J · K−1 · mol−1
- ^ ΔfH°, 1536.202 kJ · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 0 J · K−1 · mol−1
- ^ Cp°, 0 J · K−1 · mol−1
- ^ ΔfH°, 3054.07 kJ · mol−1
- ^ ΔfH°, 64.77 kJ · mol−1
- ^ ΔfG°, 65.49 kJ · mol−1
- ^ S°, -99.6 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 223.066 J · K−1 · mol−1
- ^ Cp°, 33.907 J · K−1 · mol−1
- ^ ΔfH°, -23.4 kJ · mol−1
- ^ ΔfG°, 6.94 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1
- ^ ΔfH°, 457.964 kJ · mol−1
- ^ ΔfH°, -258.28 kJ · mol−1
- ^ ΔfG°, -292.02 kJ · mol−1
- ^ S°, 133.05 J · K−1 · mol−1
- ^ Cp°, -10.5 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1