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6AsBr3 + 18HNO3 → 3As2O5 + 7HBrO3 + 18NO↑ + 11HBr↑

The reaction of arsenic tribromide and nitric acid yields diarsenic pentaoxide, bromic acid, nitrogen monoxide, and hydrogen bromide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and oxidizing species
Reducing speciesReducing agent + Oxidizing speciesOxidizing agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
AsBr3Arsenic tribromide6
Reducing
Reducing
HNO3Nitric acid18
Oxidizing
Oxidizing

Products

Chemical formulaNameCoefficientTypeType in general
equation
As2O5Diarsenic pentaoxide3
Oxidized
HBrO3Bromic acid7
Oxidized
NONitrogen monoxide18
Reduced
HBrHydrogen bromide11

Thermodynamic changes

Changes in standard condition (1)

Reaction of arsenic tribromide and nitric acid
6AsBr3Crystalline solid + 18HNO3Ionized aqueous solution
3As2O5Aqueous solution + 7HBrO3Ionized aqueous solution + 18NOGas + 11HBrGas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
2817.9
per 1 mol of
469.65
per 1 mol of
156.55
939.30
per 1 mol of
402.56
per 1 mol of
156.55
per 1 mol of
256.17

Changes in standard condition (2)

Reaction of arsenic tribromide and nitric acid
6AsBr3Crystalline solid + 18HNO3Ionized aqueous solution
3As2O5Aqueous solution + 7HBrO3Ionized aqueous solution + 18NOGas + 11HBrIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
1881.2
per 1 mol of
313.53
per 1 mol of
104.51
627.07
per 1 mol of
268.74
per 1 mol of
104.51
per 1 mol of
171.02

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
AsBr3 (cr)-197.5[1]
AsBr3 (g)-130[1]-159[1]363.87[1]79.16[1]
HNO3 (l)-174.10[1]-80.71[1]155.60[1]109.87[1]
HNO3 (g)-135.06[1]-74.72[1]266.38[1]53.35[1]
HNO3 (ai)-207.36[1]-111.25[1]146.4[1]-86.6[1]
HNO3 (l)
1 hydrate
-473.46[1]-328.77[1]216.90[1]182.46[1]
HNO3 (l)
3 hydrate
-1056.04[1]-811.09[1]346.98[1]325.14[1]
* (cr):Crystalline solid, (g):Gas, (l):Liquid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
As2O5 (cr)-924.87[1]-782.3[1]105.4[1]116.52[1]
As2O5 (aq)-951.4[1]
As2O5 (cr)
4 hydrate
-2104.6[1]
HBrO3 (ai)-67.07[1]18.60[1]161.71[1]
NO (g)90.25[1]86.55[1]210.761[1]29.844[1]
HBr (g)-36.40[1]-53.45[1]198.695[1]29.142[1]
HBr (ai)-121.55[1]-103.96[1]82.4[1]-141.8[1]
* (cr):Crystalline solid, (aq):Aqueous solution, (ai):Ionized aqueous solution, (g):Gas

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)