6NO + 5LiOH → 5LiNO2 + NH3 + H2O
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- Reaction of nitrogen monoxide and lithium hydroxide
The reaction of nitrogen monoxide and lithium hydroxide yields lithium nitrite, ammonia, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of nitrogen monoxide and lithium hydroxide
General equation
- Reaction of self redoxing species and base
- Self-redoxing speciesSelf redox agent + BaseNon-redox agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of nitrogen monoxide and lithium hydroxide
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
NO | Nitrogen monoxide | 6 | – | Self redoxing |
LiOH | Lithium hydroxide | 5 | – | Base |
Products
Thermodynamic changes
Changes in standard condition
- Reaction of nitrogen monoxide and lithium hydroxide◆
ΔrG −88.1 kJ/mol K 2.72 × 1015 pK −15.43
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −310.8 | −88.1 | −736 | – |
per 1 mol of | −51.80 | −14.7 | −123 | – |
per 1 mol of | −62.16 | −17.6 | −147 | – |
per 1 mol of | −62.16 | −17.6 | −147 | – |
per 1 mol of | −310.8 | −88.1 | −736 | – |
per 1 mol of | −310.8 | −88.1 | −736 | – |
Changes in aqueous solution (1)
- Reaction of nitrogen monoxide and lithium hydroxide◆
ΔrG −147.5 kJ/mol K 6.93 × 1025 pK −25.84
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −246.49 | −147.5 | −332.2 | 186.3 |
per 1 mol of | −41.082 | −24.58 | −55.37 | 31.05 |
per 1 mol of | −49.298 | −29.50 | −66.44 | 37.26 |
per 1 mol of | −49.298 | −29.50 | −66.44 | 37.26 |
per 1 mol of | −246.49 | −147.5 | −332.2 | 186.3 |
per 1 mol of | −246.49 | −147.5 | −332.2 | 186.3 |
Changes in aqueous solution (2)
- Reaction of nitrogen monoxide and lithium hydroxide◆
ΔrG −157.5 kJ/mol K 3.92 × 1027 pK −27.59
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −280.67 | −157.5 | −413.4 | – |
per 1 mol of | −46.778 | −26.25 | −68.90 | – |
per 1 mol of | −56.134 | −31.50 | −82.68 | – |
per 1 mol of | −56.134 | −31.50 | −82.68 | – |
per 1 mol of | −280.67 | −157.5 | −413.4 | – |
per 1 mol of | −280.67 | −157.5 | −413.4 | – |
Changes in aqueous solution (3)
- Reaction of nitrogen monoxide and lithium hydroxide◆
ΔrG −141.4 kJ/mol K 5.92 × 1024 pK −24.77
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −246.9 | −141.4 | −353.7 | – |
per 1 mol of | −41.15 | −23.57 | −58.95 | – |
per 1 mol of | −49.38 | −28.28 | −70.74 | – |
per 1 mol of | −49.38 | −28.28 | −70.74 | – |
per 1 mol of | −246.9 | −141.4 | −353.7 | – |
per 1 mol of | −246.9 | −141.4 | −353.7 | – |
Changes in aqueous solution (4)
- Reaction of nitrogen monoxide and lithium hydroxide◆
ΔrG −151.4 kJ/mol K 3.34 × 1026 pK −26.52
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −281.1 | −151.4 | −434.9 | – |
per 1 mol of | −46.85 | −25.23 | −72.48 | – |
per 1 mol of | −56.22 | −30.28 | −86.98 | – |
per 1 mol of | −56.22 | −30.28 | −86.98 | – |
per 1 mol of | −281.1 | −151.4 | −434.9 | – |
per 1 mol of | −281.1 | −151.4 | −434.9 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
NO (g) | 90.25[1] | 86.55[1] | 210.761[1] | 29.844[1] |
LiOH (cr) | -484.93[1] | -438.95[1] | 42.80[1] | 49.66[1] |
LiOH (g) | -238.1[1] | -242.3[1] | 210.90[1] | 46.02[1] |
LiOH (ai) | -508.48[1] | -450.58[1] | 2.80[1] | -79.9[1] |
LiOH (ao) | -508.4[1] | -451.8[1] | 7.1[1] | – |
LiOH (cr) 1 hydrate | -788.01[1] | -680.95[1] | 71.21[1] | 79.50[1] |
* (g):Gas, (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
LiNO2 (cr) | -372.4[1] | -302.0[1] | 96[1] | – |
LiNO2 (ai) | -383.09[1] | -325.5[1] | 136.8[1] | -28.9[1] |
LiNO2 (cr) 0.5 hydrate | – | -423.3[1] | – | – |
LiNO2 (cr) 1 hydrate | -676.1[1] | -544.2[1] | 121[1] | – |
NH3 (g) | -46.11[1] | -16.45[1] | 192.45[1] | 35.06[1] |
NH3 (ao) | -80.29[1] | -26.50[1] | 111.3[1] | – |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (ao):Un-ionized aqueous solution, (l):Liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 90.25 kJ · mol−1
- ^ ΔfG°, 86.55 kJ · mol−1
- ^ S°, 210.761 J · K−1 · mol−1
- ^ Cp°, 29.844 J · K−1 · mol−1
- ^ ΔfH°, -484.93 kJ · mol−1
- ^ ΔfG°, -438.95 kJ · mol−1
- ^ S°, 42.80 J · K−1 · mol−1
- ^ Cp°, 49.66 J · K−1 · mol−1
- ^ ΔfH°, -238.1 kJ · mol−1
- ^ ΔfG°, -242.3 kJ · mol−1
- ^ S°, 210.90 J · K−1 · mol−1
- ^ Cp°, 46.02 J · K−1 · mol−1
- ^ ΔfH°, -508.48 kJ · mol−1
- ^ ΔfG°, -450.58 kJ · mol−1
- ^ S°, 2.80 J · K−1 · mol−1
- ^ Cp°, -79.9 J · K−1 · mol−1
- ^ ΔfH°, -508.4 kJ · mol−1
- ^ ΔfG°, -451.8 kJ · mol−1
- ^ S°, 7.1 J · K−1 · mol−1
- ^ ΔfH°, -788.01 kJ · mol−1
- ^ ΔfG°, -680.95 kJ · mol−1
- ^ S°, 71.21 J · K−1 · mol−1
- ^ Cp°, 79.50 J · K−1 · mol−1
- ^ ΔfH°, -372.4 kJ · mol−1
- ^ ΔfG°, -302.0 kJ · mol−1
- ^ S°, 96. J · K−1 · mol−1
- ^ ΔfH°, -383.09 kJ · mol−1
- ^ ΔfG°, -325.5 kJ · mol−1
- ^ S°, 136.8 J · K−1 · mol−1
- ^ Cp°, -28.9 J · K−1 · mol−1
- ^ ΔfG°, -423.3 kJ · mol−1
- ^ ΔfH°, -676.1 kJ · mol−1
- ^ ΔfG°, -544.2 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1
- ^ ΔfH°, -46.11 kJ · mol−1
- ^ ΔfG°, -16.45 kJ · mol−1
- ^ S°, 192.45 J · K−1 · mol−1
- ^ Cp°, 35.06 J · K−1 · mol−1
- ^ ΔfH°, -80.29 kJ · mol−1
- ^ ΔfG°, -26.50 kJ · mol−1
- ^ S°, 111.3 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1