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6NO + 5LiOH → 5LiNO2 + NH3 + H2O

The reaction of nitrogen monoxide and lithium hydroxide yields lithium nitrite, ammonia, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of self redoxing species and base
Self-redoxing speciesSelf redox agent + BaseNon-redox agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NONitrogen monoxide6
Self redoxing
LiOHLithium hydroxide5
Base

Products

Chemical formulaNameCoefficientTypeType in general
equation
LiNO2Lithium nitrite5
Oxidized
NH3Ammonia1
Reduced
H2OWater1

Thermodynamic changes

Changes in standard condition

Reaction of nitrogen monoxide and lithium hydroxide
ΔrG−88.1 kJ/mol
K2.72 × 1015
pK−15.43
6NOGas + 5LiOHCrystalline solid
5LiNO2Crystalline solid + NH3Gas + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−310.8−88.1−736
per 1 mol of
−51.80−14.7−123
per 1 mol of
−62.16−17.6−147
per 1 mol of
−62.16−17.6−147
per 1 mol of
−310.8−88.1−736
per 1 mol of
−310.8−88.1−736

Changes in aqueous solution (1)

Reaction of nitrogen monoxide and lithium hydroxide
ΔrG−147.5 kJ/mol
K6.93 × 1025
pK−25.84
6NOGas + 5LiOHIonized aqueous solution
5LiNO2Ionized aqueous solution + NH3Gas + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−246.49−147.5−332.2186.3
per 1 mol of
−41.082−24.58−55.3731.05
per 1 mol of
−49.298−29.50−66.4437.26
per 1 mol of
−49.298−29.50−66.4437.26
per 1 mol of
−246.49−147.5−332.2186.3
per 1 mol of
−246.49−147.5−332.2186.3

Changes in aqueous solution (2)

Reaction of nitrogen monoxide and lithium hydroxide
ΔrG−157.5 kJ/mol
K3.92 × 1027
pK−27.59
6NOGas + 5LiOHIonized aqueous solution
5LiNO2Ionized aqueous solution + NH3Un-ionized aqueous solution + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−280.67−157.5−413.4
per 1 mol of
−46.778−26.25−68.90
per 1 mol of
−56.134−31.50−82.68
per 1 mol of
−56.134−31.50−82.68
per 1 mol of
−280.67−157.5−413.4
per 1 mol of
−280.67−157.5−413.4

Changes in aqueous solution (3)

Reaction of nitrogen monoxide and lithium hydroxide
ΔrG−141.4 kJ/mol
K5.92 × 1024
pK−24.77
6NOGas + 5LiOHUn-ionized aqueous solution
5LiNO2Ionized aqueous solution + NH3Gas + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−246.9−141.4−353.7
per 1 mol of
−41.15−23.57−58.95
per 1 mol of
−49.38−28.28−70.74
per 1 mol of
−49.38−28.28−70.74
per 1 mol of
−246.9−141.4−353.7
per 1 mol of
−246.9−141.4−353.7

Changes in aqueous solution (4)

Reaction of nitrogen monoxide and lithium hydroxide
ΔrG−151.4 kJ/mol
K3.34 × 1026
pK−26.52
6NOGas + 5LiOHUn-ionized aqueous solution
5LiNO2Ionized aqueous solution + NH3Un-ionized aqueous solution + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−281.1−151.4−434.9
per 1 mol of
−46.85−25.23−72.48
per 1 mol of
−56.22−30.28−86.98
per 1 mol of
−56.22−30.28−86.98
per 1 mol of
−281.1−151.4−434.9
per 1 mol of
−281.1−151.4−434.9

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NO (g)90.25[1]86.55[1]210.761[1]29.844[1]
LiOH (cr)-484.93[1]-438.95[1]42.80[1]49.66[1]
LiOH (g)-238.1[1]-242.3[1]210.90[1]46.02[1]
LiOH (ai)-508.48[1]-450.58[1]2.80[1]-79.9[1]
LiOH (ao)-508.4[1]-451.8[1]7.1[1]
LiOH (cr)
1 hydrate
-788.01[1]-680.95[1]71.21[1]79.50[1]
* (g):Gas, (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
LiNO2 (cr)-372.4[1]-302.0[1]96[1]
LiNO2 (ai)-383.09[1]-325.5[1]136.8[1]-28.9[1]
LiNO2 (cr)
0.5 hydrate
-423.3[1]
LiNO2 (cr)
1 hydrate
-676.1[1]-544.2[1]121[1]
NH3 (g)-46.11[1]-16.45[1]192.45[1]35.06[1]
NH3 (ao)-80.29[1]-26.50[1]111.3[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (ao):Un-ionized aqueous solution, (l):Liquid

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)