7Cu + 8Pb(NO3)2 + 10H2O → 7Cu(NO3)2 + N2H4 + 8Pb(OH)2
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- Reaction of and lead(II) nitrate under neutral condition
The reaction of , lead(II) nitrate, and water yields copper(II) nitrate, hydrazine, and lead(II) hydroxide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and lead(II) nitrate under neutral condition
General equation
- Reaction of oxidizable species and oxidizing species under neutral condition
- Oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent + H2ONon-redox agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of and lead(II) nitrate under neutral condition
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
7 | Reducing | Oxidizable | ||
Pb(NO3)2 | Lead(II) nitrate | 8 | Oxidizing | Oxidizing |
H2O | Water | 10 | – | Water |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
Cu(NO3)2 | Copper(II) nitrate | 7 | Oxidized | – |
N2H4 | Hydrazine | 1 | Reduced | – |
Pb(OH)2 | Lead(II) hydroxide | 8 | – | – |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of and lead(II) nitrate under neutral condition
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | – | – | – |
– | – | – | – | |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
per 1 mol of | – | – | – | – |
Changes in standard condition (2)
- Reaction of and lead(II) nitrate under neutral condition
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | 276.6 | – | – | – |
39.51 | – | – | – | |
per 1 mol of | 34.58 | – | – | – |
per 1 mol of | 27.66 | – | – | – |
per 1 mol of | 39.51 | – | – | – |
per 1 mol of | 276.6 | – | – | – |
per 1 mol of | 34.58 | – | – | – |
Changes in aqueous solution
- Reaction of and lead(II) nitrate under neutral condition◆
ΔrG −241.9 kJ/mol K 2.39 × 1042 pK −42.38
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −241.9 | – | – |
– | −34.56 | – | – | |
per 1 mol of | – | −30.24 | – | – |
per 1 mol of | – | −24.19 | – | – |
per 1 mol of | – | −34.56 | – | – |
per 1 mol of | – | −241.9 | – | – |
per 1 mol of | – | −30.24 | – | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(cr) | 0[1] | 0[1] | 33.150[1] | 24.435[1] |
(g) | 338.32[1] | 298.58[1] | 166.38[1] | 20.786[1] |
Pb(NO3)2 (cr) | -451.9[1] | – | – | – |
Pb(NO3)2 (ai) | -416.3[1] | -246.93[1] | 303.3[1] | – |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (l):Liquid
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Cu(NO3)2 (cr) | -302.9[1] | – | – | – |
Cu(NO3)2 (ai) | -349.95[1] | -157.02[1] | 193.3[1] | – |
Cu(NO3)2 (cr) 3 hydrate | -1217.1[1] | – | – | – |
Cu(NO3)2 (cr) 6 hydrate | -2110.8[1] | – | – | – |
N2H4 (l) | 50.63[1] | 149.34[1] | 121.21[1] | 98.87[1] |
N2H4 (g) | 95.40[1] | 159.35[1] | 238.47[1] | 49.58[1] |
N2H4 (ao) | 34.31[1] | 128.1[1] | 138[1] | – |
Pb(OH)2 (cr) | – | -452.2[1] | – | – |
Pb(OH)2 (cr) precipitated | -515.9[1] | – | – | – |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (l):Liquid, (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 33.150 J · K−1 · mol−1
- ^ Cp°, 24.435 J · K−1 · mol−1
- ^ ΔfH°, 338.32 kJ · mol−1
- ^ ΔfG°, 298.58 kJ · mol−1
- ^ S°, 166.38 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1
- ^ ΔfH°, -451.9 kJ · mol−1
- ^ ΔfH°, -416.3 kJ · mol−1
- ^ ΔfG°, -246.93 kJ · mol−1
- ^ S°, 303.3 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1
- ^ ΔfH°, -302.9 kJ · mol−1
- ^ ΔfH°, -349.95 kJ · mol−1
- ^ ΔfG°, -157.02 kJ · mol−1
- ^ S°, 193.3 J · K−1 · mol−1
- ^ ΔfH°, -1217.1 kJ · mol−1
- ^ ΔfH°, -2110.8 kJ · mol−1
- ^ ΔfH°, 50.63 kJ · mol−1
- ^ ΔfG°, 149.34 kJ · mol−1
- ^ S°, 121.21 J · K−1 · mol−1
- ^ Cp°, 98.87 J · K−1 · mol−1
- ^ ΔfH°, 95.40 kJ · mol−1
- ^ ΔfG°, 159.35 kJ · mol−1
- ^ S°, 238.47 J · K−1 · mol−1
- ^ Cp°, 49.58 J · K−1 · mol−1
- ^ ΔfH°, 34.31 kJ · mol−1
- ^ ΔfG°, 128.1 kJ · mol−1
- ^ S°, 138. J · K−1 · mol−1
- ^ ΔfG°, -452.2 kJ · mol−1
- ^ ΔfH°, -515.9 kJ · mol−1