7H2S + 8CsClO4 → 4Cs2SO4 + 3SO3 + 4Cl2 + 7H2O
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- Reaction of hydrogen sulfide and caesium perchlorate
The reaction of hydrogen sulfide and caesium perchlorate yields caesium sulfate, sulfur trioxide, , and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of hydrogen sulfide and caesium perchlorate
General equation
- Reaction of reducing species and oxidizing species
- Reducing speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of hydrogen sulfide and caesium perchlorate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
H2S | Hydrogen sulfide | 7 | Reducing | Reducing |
CsClO4 | Caesium perchlorate | 8 | Oxidizing | Oxidizing |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
Cs2SO4 | Caesium sulfate | 4 | Oxidized | – |
SO3 | Sulfur trioxide | 3 | Oxidized | – |
4 | Reduced | – | ||
H2O | Water | 7 | – | – |
Thermodynamic changes
Changes in standard condition
- Reaction of hydrogen sulfide and caesium perchlorate◆
ΔrG −5326.47 kJ/mol K 1.44 × 10933 pK −933.16
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −5406.88 | −5326.47 | −270.3 | – |
per 1 mol of | −772.411 | −760.924 | −38.61 | – |
per 1 mol of | −675.860 | −665.809 | −33.79 | – |
per 1 mol of | −1351.72 | −1331.62 | −67.58 | – |
per 1 mol of | −1802.29 | −1775.49 | −90.10 | – |
−1351.72 | −1331.62 | −67.58 | – | |
per 1 mol of | −772.411 | −760.924 | −38.61 | – |
Changes in aqueous solution (1)
- Reaction of hydrogen sulfide and caesium perchlorate◆
ΔrG −5497.64 kJ/mol K 1.40 × 10963 pK −963.14
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −5688.8 | −5497.64 | −629 | – |
per 1 mol of | −812.69 | −785.377 | −89.9 | – |
per 1 mol of | −711.10 | −687.205 | −78.6 | – |
per 1 mol of | −1422.2 | −1374.41 | −157 | – |
per 1 mol of | −1896.3 | −1832.55 | −210 | – |
−1422.2 | −1374.41 | −157 | – | |
per 1 mol of | −812.69 | −785.377 | −89.9 | – |
Changes in aqueous solution (2)
- Reaction of hydrogen sulfide and caesium perchlorate◆
ΔrG −5469.88 kJ/mol K 1.91 × 10958 pK −958.28
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −5782.4 | −5469.88 | −1038 | – |
per 1 mol of | −826.06 | −781.411 | −148.3 | – |
per 1 mol of | −722.80 | −683.735 | −129.8 | – |
per 1 mol of | −1445.6 | −1367.47 | −259.5 | – |
per 1 mol of | −1927.5 | −1823.29 | −346.0 | – |
−1445.6 | −1367.47 | −259.5 | – | |
per 1 mol of | −826.06 | −781.411 | −148.3 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
H2S (g) | -20.63[1] | -33.56[1] | 205.79[1] | 34.23[1] |
H2S (ao) | -39.7[1] | -27.83[1] | 121[1] | – |
CsClO4 (cr) | -443.09[1] | -314.26[1] | 175.06[1] | 108.28[1] |
CsClO4 (ai) | -387.61[1] | -300.54[1] | 315.1[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Cs2SO4 (cr) | -1443.02[1] | -1323.58[1] | 211.92[1] | 134.89[1] |
Cs2SO4 (g) | -1102.9[1] | – | – | – |
Cs2SO4 (ai) | -1425.82[1] | -1328.56[1] | 286.2[1] | – |
SO3 (cr) β | -454.51[1] | -374.21[1] | 70.7[1] | – |
SO3 (l) | -441.04[1] | -373.75[1] | 113.8[1] | – |
SO3 (g) | -395.72[1] | -371.06[1] | 256.76[1] | 50.67[1] |
(g) | 0[1] | 0[1] | 223.066[1] | 33.907[1] |
(ao) | -23.4[1] | 6.94[1] | 121[1] | – |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (l):Liquid, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -20.63 kJ · mol−1
- ^ ΔfG°, -33.56 kJ · mol−1
- ^ S°, 205.79 J · K−1 · mol−1
- ^ Cp°, 34.23 J · K−1 · mol−1
- ^ ΔfH°, -39.7 kJ · mol−1
- ^ ΔfG°, -27.83 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1
- ^ ΔfH°, -443.09 kJ · mol−1
- ^ ΔfG°, -314.26 kJ · mol−1
- ^ S°, 175.06 J · K−1 · mol−1
- ^ Cp°, 108.28 J · K−1 · mol−1
- ^ ΔfH°, -387.61 kJ · mol−1
- ^ ΔfG°, -300.54 kJ · mol−1
- ^ S°, 315.1 J · K−1 · mol−1
- ^ ΔfH°, -1443.02 kJ · mol−1
- ^ ΔfG°, -1323.58 kJ · mol−1
- ^ S°, 211.92 J · K−1 · mol−1
- ^ Cp°, 134.89 J · K−1 · mol−1
- ^ ΔfH°, -1102.9 kJ · mol−1
- ^ ΔfH°, -1425.82 kJ · mol−1
- ^ ΔfG°, -1328.56 kJ · mol−1
- ^ S°, 286.2 J · K−1 · mol−1
- ^ ΔfH°, -454.51 kJ · mol−1
- ^ ΔfG°, -374.21 kJ · mol−1
- ^ S°, 70.7 J · K−1 · mol−1
- ^ ΔfH°, -441.04 kJ · mol−1
- ^ ΔfG°, -373.75 kJ · mol−1
- ^ S°, 113.8 J · K−1 · mol−1
- ^ ΔfH°, -395.72 kJ · mol−1
- ^ ΔfG°, -371.06 kJ · mol−1
- ^ S°, 256.76 J · K−1 · mol−1
- ^ Cp°, 50.67 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 223.066 J · K−1 · mol−1
- ^ Cp°, 33.907 J · K−1 · mol−1
- ^ ΔfH°, -23.4 kJ · mol−1
- ^ ΔfG°, 6.94 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1