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8NO2 + 3Pb(OH)2 → NH4NO3 + 3Pb(NO3)2 + H2O

The reaction of nitrogen dioxide and lead(II) hydroxide yields ammonium nitrate, lead(II) nitrate, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of self redoxing species and base
Self-redoxing speciesSelf redox agent + BaseNon-redox agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NO2Nitrogen dioxide8
Self redoxing
Pb(OH)2Lead(II) hydroxide3
Base

Products

Chemical formulaNameCoefficientTypeType in general
equation
NH4NO3Ammonium nitrate1
Redoxed product
Pb(NO3)2Lead(II) nitrate3
Oxidized
H2OWater1

Thermodynamic changes

Changes in standard condition (1)

Reaction of nitrogen dioxide and lead(II) hydroxide
8NO2Gas + 3Pb(OH)2Crystalline solid
NH4NO3Crystalline solid + 3Pb(NO3)2Crystalline solid + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of
per 1 mol of
per 1 mol of

Changes in standard condition (2)

Reaction of nitrogen dioxide and lead(II) hydroxide
8NO2Gas + 3Pb(OH)2Crystalline solidprecipitated
NH4NO3Crystalline solid + 3Pb(NO3)2Crystalline solid + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−724.8
per 1 mol of
−90.60
per 1 mol of
−241.6
per 1 mol of
−724.8
per 1 mol of
−241.6
per 1 mol of
−724.8

Changes in aqueous solution

Reaction of nitrogen dioxide and lead(II) hydroxide
ΔrG−222.4 kJ/mol
K9.18 × 1038
pK−38.96
8NO2Gas + 3Pb(OH)2Crystalline solid
NH4NO3Ionized aqueous solution + 3Pb(NO3)2Ionized aqueous solution + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−222.4
per 1 mol of
−27.80
per 1 mol of
−74.13
per 1 mol of
−222.4
per 1 mol of
−74.13
per 1 mol of
−222.4

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NO2 (g)33.18[1]51.31[1]240.06[1]37.20[1]
Pb(OH)2 (cr)-452.2[1]
Pb(OH)2 (cr)
precipitated
-515.9[1]
* (g):Gas, (cr):Crystalline solid

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NH4NO3 (cr)-365.56[1]-183.87[1]151.08[1]139.3[1]
NH4NO3 (ai)-339.87[1]-190.56[1]259.8[1]-6.7[1]
Pb(NO3)2 (cr)-451.9[1]
Pb(NO3)2 (ai)-416.3[1]-246.93[1]303.3[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (l):Liquid, (g):Gas

References

List of references

  1. 1