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8NO + 2CsOH → 2CsNO3 + 3N2O + H2O

The reaction of nitrogen monoxide and caesium hydroxide yields caesium nitrate, dinitrotgen monoxide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of self redoxing species and base
Self-redoxing speciesSelf redox agent + BaseNon-redox agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NONitrogen monoxide8
Self redoxing
CsOHCaesium hydroxide2
Base

Products

Chemical formulaNameCoefficientTypeType in general
equation
CsNO3Caesium nitrate2
Oxidized
N2ODinitrotgen monoxide3
Reduced
H2OWater1

Thermodynamic changes

Changes in standard condition

Reaction of nitrogen monoxide and caesium hydroxide
8NOGas + 2CsOHCrystalline solid
2CsNO3Crystalline solid + 3N2OGas + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−939.16
per 1 mol of
−117.39
per 1 mol of
−469.58
per 1 mol of
−469.58
−313.05
per 1 mol of
−939.16

Changes in aqueous solution (1)

Reaction of nitrogen monoxide and caesium hydroxide
ΔrG−524.97 kJ/mol
K9.35 × 1091
pK−91.97
8NOGas + 2CsOHIonized aqueous solution
2CsNO3Ionized aqueous solution + 3N2OGas + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−716.42−524.97−642.2
per 1 mol of
−89.552−65.621−80.28
per 1 mol of
−358.21−262.49−321.1
per 1 mol of
−358.21−262.49−321.1
−238.81−174.99−214.1
per 1 mol of
−716.42−524.97−642.2

Changes in aqueous solution (2)

Reaction of nitrogen monoxide and caesium hydroxide
8NOGas + 2CsOHIonized aqueous solution
2CsNO3Ionized aqueous solution + 3N2OAqueous solution + H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−794.3
per 1 mol of
−99.29
per 1 mol of
−397.1
per 1 mol of
−397.1
−264.8
per 1 mol of
−794.3

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NO (g)90.25[1]86.55[1]210.761[1]29.844[1]
CsOH (cr)-417.23[1]
CsOH (g)-247[1]-247[1]254.83[1]49.71[1]
CsOH (ai)-488.27[1]-449.25[1]122.30[1]
CsOH (cr)
1 hydrate
-754.04[1]
* (g):Gas, (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
CsNO3 (cr)-505.97[1]-406.54[1]155.2[1]
CsNO3 (g)-374.0[1]
CsNO3 (ai)-465.64[1]-403.27[1]279.5[1]-99[1]
N2O (g)82.05[1]104.20[1]219.85[1]38.45[1]
N2O (aq)56.1[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (aq):Aqueous solution, (l):Liquid

References

List of references

  1. 1