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8Na + RbClO4 → 4Na2O + RbCl

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Reaction of sodium and rubidium perchlorate
8NaSodium + RbClO4Rubidium perchlorate
⟶
4Na2OSodium oxide + RbClRubidium chloride

The reaction of sodium and rubidium perchlorate yields sodium oxide and rubidium chloride (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of sodium and rubidium perchlorate
8NaSodium + RbClO4Rubidium perchlorate
⟶
4Na2OSodium oxide + RbClRubidium chloride

General equation

Reaction of reducing species and oxidizing species
Reducing speciesReducing agent + Oxidizing speciesOxidizing agent
⟶
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of sodium and rubidium perchlorate

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NaSodium8
Reducing
Reducing
RbClO4Rubidium perchlorate1
Oxidizing
Oxidizing

Products

Chemical formulaNameCoefficientTypeType in general
equation
Na2OSodium oxide4
Oxidized
–
RbClRubidium chloride1
Reduced
–

Thermodynamic changes

Changes in standard condition

Reaction of sodium and rubidium perchlorate
◆
ΔrG−1602.74 kJ/mol
K6.14 × 10280
pK−280.79
8NaCrystalline solid + RbClO4Crystalline solid
⟶
4Na2OCrystalline solid + RbClCrystalline solid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−1655.00−1602.74−174.6–
per 1 mol of
−206.875−200.343−21.82–
−1655.00−1602.74−174.6–
per 1 mol of
−413.750−400.685−43.65–
per 1 mol of
−1655.00−1602.74−174.6–

Changes in aqueous solution

Reaction of sodium and rubidium perchlorate
◆
ΔrG−1624.53 kJ/mol
K4.03 × 10284
pK−284.61
8NaCrystalline solid + RbClO4Ionized aqueous solution
⟶
4Na2OCrystalline solid + RbClIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−1694.71−1624.53−234.8–
per 1 mol of
−211.839−203.066−29.35–
−1694.71−1624.53−234.8–
per 1 mol of
−423.678−406.132−58.70–
per 1 mol of
−1694.71−1624.53−234.8–

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na (cr)0[1]0[1]51.21[1]28.24[1]
Na (g)107.32[1]76.761[1]153.712[1]20.786[1]
RbClO4 (cr)-437.23[1]-306.90[1]161.1[1]–
RbClO4 (ai)-380.49[1]-292.51[1]303.3[1]–
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na2O (cr)-414.22[1]-375.46[1]75.06[1]69.12[1]
Na2O (g)-35.6[1]-52.3[1]261.2[1]55.2[1]
RbCl (cr)-435.35[1]-407.80[1]95.90[1]52.38[1]
RbCl (g)-228.9[1]-247.3[1]249.56[1]36.82[1]
RbCl (ai)-418.32[1]-415.20[1]177.99[1]–
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)