8Na + Rb2SO4 → 4Na2O + Rb2S
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- Reaction of and rubidium sulfate
The reaction of and rubidium sulfate yields sodium oxide and rubidium sulfide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and rubidium sulfate
General equation
- Reaction of reducing species and reducible species
- Reducing speciesReducing agent + Reducible speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of and rubidium sulfate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
8 | Reducing | Reducing | ||
Rb2SO4 | Rubidium sulfate | 1 | Oxidizing | Reducible |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
Na2O | Sodium oxide | 4 | Oxidized | – |
Rb2S | Rubidium sulfide | 1 | Reduced | – |
Thermodynamic changes
Changes in standard condition
- Reaction of and rubidium sulfate
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −582.0 | – | – | – |
−72.75 | – | – | – | |
per 1 mol of | −582.0 | – | – | – |
per 1 mol of | −145.5 | – | – | – |
per 1 mol of | −582.0 | – | – | – |
Changes in aqueous solution
- Reaction of and rubidium sulfate◆
ΔrG −671.3 kJ/mol K 4.04 × 10117 pK −117.61
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −714.7 | −671.3 | −144.2 | – |
−89.34 | −83.91 | −18.02 | – | |
per 1 mol of | −714.7 | −671.3 | −144.2 | – |
per 1 mol of | −178.7 | −167.8 | −36.05 | – |
per 1 mol of | −714.7 | −671.3 | −144.2 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(cr) | 0[1] | 0[1] | 51.21[1] | 28.24[1] |
(g) | 107.32[1] | 76.761[1] | 153.712[1] | 20.786[1] |
Rb2SO4 (cr) | -1435.61[1] | -1316.89[1] | 197.44[1] | 134.06[1] |
Rb2SO4 (g) | -1068.6[1] | – | – | – |
Rb2SO4 (ai) | -1411.60[1] | -1312.50[1] | 263.2[1] | – |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Na2O (cr) | -414.22[1] | -375.46[1] | 75.06[1] | 69.12[1] |
Na2O (g) | -35.6[1] | -52.3[1] | 261.2[1] | 55.2[1] |
Rb2S (cr) | -360.7[1] | – | – | – |
Rb2S (ai) | -469.4[1] | -482.0[1] | 228.4[1] | – |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 51.21 J · K−1 · mol−1
- ^ Cp°, 28.24 J · K−1 · mol−1
- ^ ΔfH°, 107.32 kJ · mol−1
- ^ ΔfG°, 76.761 kJ · mol−1
- ^ S°, 153.712 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1
- ^ ΔfH°, -1435.61 kJ · mol−1
- ^ ΔfG°, -1316.89 kJ · mol−1
- ^ S°, 197.44 J · K−1 · mol−1
- ^ Cp°, 134.06 J · K−1 · mol−1
- ^ ΔfH°, -1068.6 kJ · mol−1
- ^ ΔfH°, -1411.60 kJ · mol−1
- ^ ΔfG°, -1312.50 kJ · mol−1
- ^ S°, 263.2 J · K−1 · mol−1
- ^ ΔfH°, -414.22 kJ · mol−1
- ^ ΔfG°, -375.46 kJ · mol−1
- ^ S°, 75.06 J · K−1 · mol−1
- ^ Cp°, 69.12 J · K−1 · mol−1
- ^ ΔfH°, -35.6 kJ · mol−1
- ^ ΔfG°, -52.3 kJ · mol−1
- ^ S°, 261.2 J · K−1 · mol−1
- ^ Cp°, 55.2 J · K−1 · mol−1
- ^ ΔfH°, -360.7 kJ · mol−1
- ^ ΔfH°, -469.4 kJ · mol−1
- ^ ΔfG°, -482.0 kJ · mol−1
- ^ S°, 228.4 J · K−1 · mol−1