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4HgCl2 + 2H2O 💧⚡→ 2Hg2Cl2 + HClO2 + 3HCl↑

Electrolysis of aqueous mercury(II) chloride with water as non-redox agent

Electrolysis of aqueous mercury(II) chloride yields mercury(I) chloride, chlorous acid, and hydrogen chloride (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Electrolysis of aqueous mercury(II) chloride with water as non-redox agent

General equation

Electrolysis of aqueous solution with water as non redox agent
Miscible with water/Very soluble in water/Soluble in waterSelf redox agent + H2ONon-redox agent
💧⚡
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Electrolysis of aqueous mercury(II) chloride with water as non-redox agent

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
HgCl2Mercury(II) chloride4
Self redox agent
Soluble in water
H2OWater2
Water

Products

Chemical formulaNameCoefficientTypeType in general
equation
Hg2Cl2Mercury(I) chloride2
Reduced
HClO2Chlorous acid1
Oxidized
HClHydrogen chloride3

Thermodynamic changes

Changes in standard condition (1)

Electrolysis of aqueous mercury(II) chloride with water as non-redox agent
ΔrG465.6 kJ/mol
K0.27 × 10−81
pK81.57
4HgCl2Un-ionized aqueous solution + 2H2OLiquid
💧⚡
2Hg2Cl2Crystalline solid + HClO2Un-ionized aqueous solution + 3HClGas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
577.6465.6374
144.4116.493.5
per 1 mol of
288.8232.8187
288.8232.8187
per 1 mol of
577.6465.6374
per 1 mol of
192.5155.2125

Changes in standard condition (2)

Electrolysis of aqueous mercury(II) chloride with water as non-redox agent
ΔrG357.8 kJ/mol
K0.21 × 10−62
pK62.68
4HgCl2Un-ionized aqueous solution + 2H2OLiquid
💧⚡
2Hg2Cl2Crystalline solid + HClO2Un-ionized aqueous solution + 3HClIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
353.0357.8−17
88.2589.45−4.3
per 1 mol of
176.5178.9−8.5
176.5178.9−8.5
per 1 mol of
353.0357.8−17
per 1 mol of
117.7119.3−5.7

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
HgCl2 (cr)-224.3[1]-178.6[1]146.0[1]
HgCl2 (ao)-216.3[1]-173.2[1]155[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (ao):Un-ionized aqueous solution, (l):Liquid, (g):Gas

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Hg2Cl2 (cr)-265.22[1]-210.745[1]192.5[1]
HClO2 (ao)-51.9[1]5.9[1]188.3[1]
HCl (g)-92.307[1]-95.299[1]186.908[1]29.12[1]
HCl (ai)-167.159[1]-131.228[1]56.5[1]-136.4[1]
* (cr):Crystalline solid, (ao):Un-ionized aqueous solution, (g):Gas, (ai):Ionized aqueous solution

References

List of references

  1. 1