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2LiCl 🔥⚡→ 2Li + Cl2

Molten salt electrolysis of lithium chloride

Molten salt electrolysis of lithium chloride yields lithium and chlorine. This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

Molten salt electrolysis of lithium chloride

General equation

Molten salt electrolysis
SaltSelf redox agent
🔥⚡
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Molten salt electrolysis of lithium chloride

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
LiClLithium chloride2
Self redox agent
Salt

Products

Chemical formulaNameCoefficientTypeType in general
equation
LiLithium2
Reduced
Cl2Chlorine1
Oxidized

Thermodynamic changes

Changes in standard condition

Molten salt electrolysis of lithium chloride
ΔrG768.74 kJ/mol
K0.21 × 10−134
pK134.68
2LiClCrystalline solid
🔥⚡
2LiCrystalline solid + Cl2Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
817.22768.74162.65−12.53
per 1 mol of
408.61384.3781.325−6.265
per 1 mol of
408.61384.3781.325−6.265
per 1 mol of
817.22768.74162.65−12.53

Changes in aqueous solution (1)

Molten salt electrolysis of lithium chloride
ΔrG849.16 kJ/mol
K0.17 × 10−148
pK148.77
2LiClIonized aqueous solution
🔥⚡
2LiCrystalline solid + Cl2Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
891.28849.16141.5219.0
per 1 mol of
445.64424.5870.75109.5
per 1 mol of
445.64424.5870.75109.5
per 1 mol of
891.28849.16141.5219.0

Changes in aqueous solution (2)

Molten salt electrolysis of lithium chloride
ΔrG856.10 kJ/mol
K0.10 × 10−149
pK149.98
2LiClIonized aqueous solution
🔥⚡
2LiCrystalline solid + Cl2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
867.9856.1039
per 1 mol of
433.9428.0520
per 1 mol of
433.9428.0520
per 1 mol of
867.9856.1039

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
LiCl (cr)-408.61[1]-384.37[1]59.33[1]47.99[1]
LiCl (g)-195.4[1]-216.7[1]212.824[1]33.22[1]
LiCl (ai)-445.64[1]-424.58[1]69.9[1]-67.8[1]
LiCl (cr)
1 hydrate
-712.58[1]-631.80[1]102.84[1]
LiCl (cr)
2 hydrate
-1012.65[1]
LiCl (cr)
3 hydrate
-1311.3[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Li (cr)0[1]0[1]29.12[1]24.77[1]
Li (g)159.37[1]126.66[1]138.77[1]20.786[1]
Cl2 (g)0[1]0[1]223.066[1]33.907[1]
Cl2 (ao)-23.4[1]6.94[1]121[1]
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution

References

List of references

  1. 1