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Permanganic acid

Chemical structure of permanganic acid

Permanganic acid is an inorganic compound with formula HMnO4.

Table of contents
  1. 1Names
  2. 2Formulae and structures
  3. 3Properties
  4. 4Constituents
  5. 5Thermodynamic properties
  6. 6Solubility
  7. 7Preparations
  8. 8Chemical reactions
  9. 9Related substances
  10. 10Related categories

Names

List of substance names

Nomenclature
Name
Typical name
Permanganic acid
Compositional nomenclature
Hydrogen permanganate
Additive nomenclature
Hydroxidotrioxidomanganese
Hydrogen nomenclature
Hydrogen(tetraoxidomanganate)(1−)
IUPAC acceptable common names
Permanganic acid
Other names
Manganic(VII) acid

Formulae and structures

List of formulae

Formula name
Formula
Typical formula
HMnO4
Molecular formula
HMnO4
Compositional formula
HMnO4
Structural formula
Chemical structure of permanganic acid
Other structural formulas
Chemical structure of permanganic acid with double bonds
Lewis structure
Lewis structure of permanganic acid
Colored Lewis structure
Colored Lewis structure of permanganic acid

Properties

List of substance properties

Item
Value
Name
Permanganic acid
Formula
HMnO4
Appearance
Purple solid
Odor
Odorless
Molar mass
119.942 g/mol
Density
Melting point
Boiling point

Constituents

Constituent atoms

AtomNameOxidation stateNumber
HHydrogen+11
MnMangenese+71
OOxygen−24

Ratio of atoms

AtomAtomic weightNumberAtomic ratioWeight ratio
H1.008116.67%0.84%
Mn54.938116.67%45.80%
O15.999466.67%53.36%
HMnOAtomic ratio
MnOWeight ratio

Thermodynamic properties

Phase transition properties

Item
Value
Enthalpy of fusion
Enthalpy of vaporization
Enthalpy of vaporization at 25°C
Enthalpy of other transition

Solubility

Qualitative solubility

Reactive
Miscible
Very soluble
Soluble
Slightly soluble
Very slightly soluble
Insoluble

Preparations

Reaction of acidic oxide and water

The reaction of manganese(VII) oxide and water yields permanganic acid.

Chemical reactions

Electrolytic dissociation

Electrolytic dissociation of permanganic acid yields hydrogen ion and permanganate ion.

Reaction with base

The reaction of permanganic acid and base yields salt and water.

Reaction with basic oxide

The reaction of basic oxide and permanganic acid yields salt and water.

Reaction with salt of weak acid

The reaction of salt of weak acid and permanganic acid yields salt of strong acid and weak acid.

Reaction with salt of volatile acid

The reaction of salt of volatile acid and permanganic acid yields salt of non volatile acid and volatile acid.

Reaction with dehydrating acidic oxide

The reaction of permanganic acid and dehydrating acidic oxide yields manganese(VII) oxide and oxoacid.

Reaction with inactive metal

The reaction of silver and permanganic acid yields silver(I) permanganate, manganese(IV) oxide, and water.

Reaction with self-redoxing species

The reaction of self-redoxing species and permanganic acid yields a variety of products.

Reaction with reducing species

The reaction of reducing species and permanganic acid yields a variety of products.

Reaction with oxidizable species

The reaction of oxidizable species and permanganic acid yields a variety of products.

Reaction with oxidizable species under acidic condition

The reaction of oxidizable species, permanganic acid, and hydrogen ion yields a variety of products.

Reaction of copper and permanganic acid under acidic condition
5CuCopper + 2HMnO4Permanganic acid + 14H+Hydrogen ion
🔥
5Cu2+Copper(II) ion + 2Mn2+Manganese(II) ion + 8H2OWater
Reaction of copper and permanganic acid under acidic condition
2CuCopper + HMnO4Permanganic acid + 7H+Hydrogen ion
🔥
2Cu2+Copper(II) ion + Mn3+Manganese(III) ion + 4H2OWater
Reaction of potassium iodide and permanganic acid under acidic condition
10KIPotassium iodide + 2HMnO4Permanganic acid + 14H+Hydrogen ion
10K+Potassium ion + 5I2Iodine + 2Mn2+Manganese(II) ion + 8H2OWater
Reaction of potassium iodide and permanganic acid under acidic condition
4KIPotassium iodide + HMnO4Permanganic acid + 7H+Hydrogen ion
4K+Potassium ion + 2I2Iodine + Mn3+Manganese(III) ion + 4H2OWater

Reaction with hardly oxidizable species

The reaction of hardly oxidizable species and permanganic acid yields a variety of products.

Reaction with hardly oxidizable species under acidic condition

The reaction of hardly oxidizable species, permanganic acid, and hydrogen ion yields a variety of products.

Reaction of hydrogen chloride and permanganic acid under acidic condition
10HClHydrogen chloride + 2HMnO4Permanganic acid + 4H+Hydrogen ion
5Cl2Chlorine + 2Mn2+Manganese(II) ion + 8H2OWater
Reaction of hydrogen chloride and permanganic acid under acidic condition
4HClHydrogen chloride + HMnO4Permanganic acid + 3H+Hydrogen ion
2Cl2Chlorine + Mn3+Manganese(III) ion + 4H2OWater
Reaction of gold and permanganic acid under acidic condition
5AuGold + 3HMnO4Permanganic acid + 21H+Hydrogen ion
🔥
5Au3+Gold(III) ion + 3Mn2+Manganese(II) ion + 12H2OWater
Reaction of gold and permanganic acid under acidic condition
4AuGold + 3HMnO4Permanganic acid + 21H+Hydrogen ion
🔥
4Au3+Gold(III) ion + 3Mn3+Manganese(III) ion + 12H2OWater
Reaction of sodium chloride and permanganic acid under acidic condition
10NaClSodium chloride + 2HMnO4Permanganic acid + 14H+Hydrogen ion
10Na+Sodium ion + 5Cl2Chlorine + 2Mn2+Manganese(II) ion + 8H2OWater

Precipitation reaction

When a certain chemical species is present in aqueous solution, it reacts with permanganic acid to form a precipitate.

Electrolysis of aqueous solution

Electrolysis of aqueous permanganic acid yields a variety of products.

Electrolysis of water
ΔrG474.258 kJ/mol
K0.82 × 10−83
pK83.09
Electrolysis of aqueous permanganic acid with water as non-redox agent
4HMnO4Permanganic acid + 2H2OWater
💧⚡
4H2MnO4Manganic acid + O2Oxygen
Electrolysis of aqueous permanganic acid with water as non-redox agent
2HMnO4Permanganic acid + 2H2OWater
💧⚡
2H2MnO4Manganic acid + H2O2Hydrogen peroxide

Decomposition

Decomposition of permanganic acid yields a variety of products.