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Potassium hydride

Chemical structure of potassium hydride

Potassium hydride is an inorganic compound with formula KH.

Table of contents
  1. 1Names
  2. 2Formulae and structures
  3. 3Properties
  4. 4Constituents
  5. 5Thermodynamic properties
  6. 6Solubility
  7. 7Preparations
  8. 8Chemical reactions
  9. 9References
  10. 10Related substances
  11. 11Related categories

Names

List of substance names

Nomenclature
Name
Typical name
Potassium hydride
Compositional nomenclature
Potassium hydride
Additive nomenclature
Hydridopotassium
Monohydridopotassium

Formulae and structures

List of formulae

Formula name
Formula
Typical formula
KH
Compositional formula
KH
Structural formula
Chemical structure of potassium hydride
Lewis structure
Lewis structure of potassium hydride
Colored Lewis structure
Colored Lewis structure of potassium hydride

Properties

List of substance properties

Item
Value
Name
Potassium hydride
Formula
KH
Appearance
Gray solid
Odor
Odorless
Molar mass
40.106 g/mol
Density
1.43 g/cm3[1]
Solid
Melting point
417 °C[1]
Decompose → K, H2
Boiling point

Constituents

Constituent ions

IonNameCharge numberNumber
K+Potassium ion11
HHydride ion-11

Constituent atoms

AtomNameOxidation stateNumber
KPotassium+11
HHydrogen−11

Ratio of atoms

AtomAtomic weightNumberAtomic ratioWeight ratio
K39.0983150.00%97.49%
H1.008150.00%2.51%
KHAtomic ratio
KHWeight ratio

Thermodynamic properties

Phase transition properties

Item
Value
Enthalpy of fusion
21 kJ · mol−1[2]
at 619°C
Enthalpy of vaporization
Enthalpy of vaporization at 25°C
Enthalpy of other transition

Standard thermodynamic properties

State
Standard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Crystalline solid−57.74[3]
Gas130.[3]113.[3]192.41[3]31.049[3]

Solubility

Qualitative solubility

Reactive
Miscible
Very soluble
Soluble
Slightly soluble
Very slightly soluble
Insoluble

Preparations

Reaction of metal and nonmetal

The reaction of potassium and hydrogen yields potassium hydride.

Reaction of nonmetal and hydroxide base

The reaction of nonmetal and hydroxide base can yield potassium hydride.

Chemical reactions

Reaction with oxidizing species

The reaction of potassium hydride and oxidizing species yields a variety of products.

Reaction with reducible species

The reaction of potassium hydride and reducible species yields a variety of products.

Reaction with hardly reducible species

The reaction of potassium hydride and hardly reducible species yields a variety of products.

Reaction with reducing species

The reaction of sodium and potassium hydride yields sodium hydride and potassium.

References

List of references

  1. 1
    James G. Speight (2017)
    Lange's Handbook of Chemistry, 17th edition
    McGraw Hill Education

  2. 2
    John R. Rumble Jr, David R. Lide, Thomas J. Bruno (2019)
    CRC Handbook of Chemistry and Physics 100th Edition
    CRC Press

  3. 3
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)